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Section A. General Organic Synthesis

Section Convener: Dr. Pedro Merino, University of Zaragoza (Spain), pmerino@posta.unizar.es
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[a0001] Recent Developments on the Use of  Triphenylphosphonium Protecting Group in the Synthesis of Substituted Hydrazines
Olga Tsubrik and Uno Mäeorg
Comments and Discussion

[a0002] Synthesis of 1,3-Dideoxy-2,5-nondiulose Derivatives by Highly Stereocontrolled Alkylation of Protected Diacetone Hexulose Aldehydes
Isidoro Izquierdo Cubero* , María T. Plaza López-Espinosa, Rafael Robles Díaz, Antonio J. Mota Ávila and Francisco Franco Montalbán
Comments and Discussion

[a0003] the Influence of Solvents and Catalysts on the Thermal Behavior of Azidohetarenes in DSC Measurements
Wolfgang Stadlbauer * and Gerhard Hojas
Comments and Discussion

[a0004] 3-Alkoxy-2-Lithiocyclohexene: a New and Stable Non-Anionic B-Functionalised Organolithium Intermediate
Inmaculada Gómez, Diego J. Ramón and Miguel Yus*
Comments and Discussion

[a0005] Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant
Pawel Kazmierczak, Lech Skulski* and Lukasz Kraszkiewicz
Comments and Discussion

[a0006] One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine,
Nicolas Obeid and Lech Skulski*
Comments and Discussion

[a0007] One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the Oxidant
Anna Kryska and Lech Skulski*
Comments and Discussion

[a0008] The Vilsmeier Reaction as a Tool for the Functionalization of 6-Unsubstituted Pyrido[2,3-d]pyrimidine-2,4-diones
U. Girreser, D. Heber* and M. Schütt
Comments and Discussion

[a0009] A Direct Synthesis of Pyrrolidines Including Nornicotine
Miguel Yus,* Tatiana Soler and Francisco Foubelo
Comments and Discussion

[a0010] Stereoselective Preparation of Optically Pure Methyl 4(R)-N-(tert-butoxycarbonyl)-4-Hydroxypyroglutamate
Pedro Merino*, Santiago Franco, Francisco Merchan, Julia Revuelta and Tomas Tejero
Comments and Discussion

[a0011] Synthesis, Crystal Structure, and Conformation of Methyl-O-acetyl-5-cyano-6-deoxy-2,3-O-isopropylidene-b
-L-gulofuranoside
Julia Micova, Bohumil Steiner, Miroslav Koóš1,* Ján Gajdoš, Vratislav Langer and Dalma Gyepesová
Comments and Discussion

[a0012] Contributions to the Mechanism of the Reactions of Isocyabates with Alcohols and Glycols
Sergiu Coseri
Comments and Discussion

[a0013] Aromaticity Study of Benzofused Thieno[3,2-b]furans: [4p+2p] vs. [2p+2p] Course of Cycloadditions of Isomeric
2-Vinyl[1]benzothieno[3,2-b]furan and 2-Vinylthieno[3,2-b][1]benzofuran
Milan Kurfurst, Pavel Pihera and Jiri Svoboda*
Comments and Discussion

[a0014] Synthesis of Tetracyclic Systems Atropoisomerism in Suzuki Coupling
Stéphanie Hesse and Gilbert Kirsch
Comments and Discussion

[a0015] Synthesis of New Substituted Thieno[b]azepinediones
Evelyne Migianu and Gilbert Kirsch
Comments and Discussion

[a0016] New Procedure for the Synthesis of 3-Aryl-2h-Azirine-2-Carboxaldehydes
Raúl-Ángel Orenes,Mateo Alajarín, Ángel Vidal andAurelia Pastor
Comments and Discussion

[a0017] Heterocumulenes as the Dienic Component in Intramolecular [4+2] Cycloadditions
Mª del Mar Ortín-Avilés, Mateo Alajarín, Ángel Vidal and Fulgencio Tovar
Comments and Discussion

[a0018] Imino Ketenimines on an Ortho-Benzylic Scaffold
Fulgencio Tovar, Mateo Alajarín,Ángel Vidaland Delia Bautista
Comments and Discussion

[a0019] Synthesis of Substttuted Thieno[2,3-b]Pyrroles by Using Isothiocyanates
Geoffroy Sommen, Alain Comel, and Gilbert Kirsch*
Comments and Discussion

[a0020] A Simple, Highly Efficient Arylation of Ketones Catalyzed by Palladium
Fátima Churruca, Raul SanMartin,  Isabel Moreno, Imanol Tellitu and Esther Domínguez*
Comments and Discussion

[a0021] Pifa Mediated Synthesis of Heterocycle-fused Quinolinones
M. Teresa Herrero, Imanol Tellitu, Susana Hernández, and Esther Domínguez,*
Comments and Discussion

[a0022] Preparation of Heterobicycles and -tricycles by Retro Diels-Alder reaction
F. Miklós, A. E. Szabó, G. Stájer, P. Sohár
Comments and Discussion

[a0023] New Perspectives in the Synthesis of Hexahydro-pyrrolo[2,1-a]isoquinolines
Cécile Coindet, Alain Comel and Gilbert Kirsch
Comments and Discussion

[a0024] A Novel Route to a Norbornane Fused 1,2,7-triazabicyclo[3.3.0]oct-2-ene by Thermal Rearrangement of
a Cyclobutano-triazoline Diester
Davor Margetic*, Ronald N. Warrener and Douglas N. Butler
Comments and Discussion

[a0025] Intramolecular Conjugate Addition of N-tosyl Carbamates: a Stereoselective Approach to Either 4,5-Disubstituted
Oxazolidin-2-Ones and Unsaturated B-amino Esters
Cristiana Fava, Roberta Galeazzi,  Mario Orena*, José Sepulveda-Arques and Eugenia Maria Gonzalez-Rosende*
Comments and Discussion

[a0026] Synthesis and Reactions of Some Novel 3-Prazolyl-2-quinolinones
Mohamed Abass* and Elham S. Othman
Comments and Discussion

[a0027] One-Pot Synthesis of 4-Pyridone form 4-Nitropyridine-N-Oxide
Vladimir N. Bulavka and Igor’ I. Boiko
Comments and Discussion

[a0028] Oxidation of 4-Diethylaminobenzaldehyde N,N-Diphenylhydrazone under UV-Irradiation in Non-Polar Solvent
Vladimir N. Bulavka * and Konstantin K. Koshelev
Comments and Discussion

[a0029] Oxidative Iodination of Tetralin and Indan
Vladimir N. Bulavka
Comments and Discussion

[a0030] Design of a New Chiral Macrobicyclic Tris(phosphazide) with One Alkyl-N3P Arm
José Berná, Mateo Alajarín and Carmen López-Leonardo
Comments and Discussion

[a0031] Sulfinimines as Enophiles in Ene Reactions with Alkenes
Aurelia Pastor and Mateo Alajarín
Comments and Discussion

[a0032] 7-Oxa-Norbornadiene-2,3-Dicarboximide: An Elusive, Highly Reactive Dienophile
Davor Margetic*, Douglas N. Butler and Ronald N. Warrener
Comments and Discussion

[a0033] Thienylsubstituted Derivatives of a-Aminobutanoic acid. Practical Approach to Enantiomerically Pure g-Hydroxy-a-aminooctanoic and g-Hydroxy-a-aminononanoic Acids.
Dusan Berkes, Vladimír Gubala and Frantisek Povazanec
Comments and Discussion

[a0034] A New Synthesis of the Pyrrolo[1,2-a][3,1,6]benzothiadiazocine Ring System from 1-{[1-(2-nitrophenyl)-1H-pyrrol-2-yl]sulfinyl} derivatives
Athanasios Kimbaris, Jonathan Cobb and George Varvounis*
Comments and Discussion

[a0035] Alkylation Products of 2-Tosylaminopyrimidines as Inhibitors of Leukocyte Functions
J. Lasri M. E. González-Rosende, J. Sepúlveda-Arques *, P. Fernández, A. Ubed, and  I. Guillén
Comments and Discussion

[a0036] Naphthalenes 1,4-disubstituted as Dienophiles in Diels-Alder Reactions
E. Paredes, B. Biolatto, and M. Kneeteman and P. Mancini*
Comments and Discussion

[a0037] Proximity Effects: the Observation by 1H NMR of Steric Compression of the Methano Bridge Protons of Polycyclic Norbornanes Possessing Adjacent Carbon, Oxygen and Nitrogen Bridges
Davor Margetic*, Martin R. Johnston, Ronald N. Warrener and Douglas N. Butler
Comments and Discussion

[a0038] Efficient Deprotection of Methoxymethyl Ethers of Phenols Using a Solid Acid Catalyst with Wells-Dawson Structure
G. Romanelli,  J. C. Autino,  G. Baronetti and H. Thomas
Comments and Discussion

[a0039] An Improved Synthesis of of 5-(2,6-Dichlorophenyl)-2-(phenylthio)-6H-pyrimido[1,6-b]pyridazin-6-one (VX-745)
Matthias Treu, Ulrich Jordis* and Ving J. Lee
Comments and Discussion

[a0040] Indolylquinones as Diels-Alder Dienes: Brief Synthesis of Polyheterocyclic Quinones
Pilar López-Alvarado, Miguel Ángel Alonso, Carmen Avendaño and J. Carlos Menéndez
Comments and Discussion

[a0041] Synthesis of Spiro-2-tetrahydrofuran-3-indolin-2-ones by Swern Reaction of 3-(3-Hydroxyalkyl)indoles
Judith Steinhoff, Pilar López-Alvarado, Sonia Miranda, Carmen Avendaño and J. Carlos Menéndez
Comments and Discussion

[a0042] Selective Protection of Hydroxyl and Sulfur Groups with Trityls
Ibrahim Demirtas
Comments and Discussion

[a0043] Synthesis of Porphyrin-C60 Dyads with Potential Use in Solar Cells
Miguel Gervaldo, Fernando Fungo, Luis A. Otero, Leonides Sereno, Juana J. Silber and Edgardo N. Durantini*
Comments and Discussion

[a0044] Synthesis of Analogues of Pentamidine as Potential Anti-Pneumocystis Carinii Agents
Tien L. Huang,*  Bin Tao, Sherry F. Queener,  Isaac O. Donkor,  Jean J. Vanden Eynde and Annie Mayence
Comments and Discussion

[a0045] Synthesis of Thieno [2,3-d]-1,3-dithiol-2-thiones from Thieno [2,3-d]-1,2,3-thiadiazoles: Matryoshka-type Autoclave for High-temperature, High-pressure Thermolytic Microscale Reactions.
Ulrich Jordis*, Kaberi Bhattacharya, Philip Y. Boamah and Ving J. Lee
Comments and Discussion

[a0046] Some Heteroaromatic Organomercurials, Their Syntheses and Reactions: a Review of Own Research Works (1980-2000)
Lech Skulski* and Piotr Wroczynski*
Comments and Discussion

[a0047] Three-Component Halo Aldol Condensation of a,b-Alkyl Thioacrylates with Aldehydes Mediated by Titanium (IV) Halide
Sun Hee Kim, Han-Xun Wei, Joe J. Gao and Guigen Li*
Comments and Discussion

[a0048] The Reactivity Study on N3,N3-(3-Oxapentan-1,5-diyl)-N1-(2-phenyl-3,4- dihydroquinazolin-4-yliden)thiourea. Part 2: Reaction with Phenacyl Bromides and Chloroacetic Acid Derivatives
Walid Fathalla, Jaromir Marek and Pavel Pazdera1*
Comments and Discussion

[a0049] The Reactivity Study on N3,N3-(3-Oxapentan-1,5-diyl)-N1-(2-phenyl-3,4- dihydroquinazolin-4-yliden)Thiourea
Walid Fathalla, Michal Cajan, Jaromir Marek and Pavel Pazdera*
Comments and Discussion

[a0050] Studies towards Dibenzothiophene-S-oxide Arrays and their photochemical Reactivity
Thies Thiemann,* Kazuya Kumazoe, Kazuya Arima and Shuntaro Mataka
Comments and Discussion

[a0051] Synthesis of Spirocyclic and Fused Bicyclic 4-Hydroxyhexahydropyrimidine-2-thiones
Anatoly D. Shutalev*, Viktor B. Rybakov and Vitaly A. Trounov
Comments and Discussion

[a0052] Opportunistic Rearrangements and Ring Transformations During the Synthesis of a Novel Ring-Expanded Purine Analogue Containing a 5:8-fused Imidazo[4,5-e][1,2,4]triazocine Ring System
Friedrick N. Burnett and Ramachandra S. Hosmane*
Comments and Discussion

[a0053] Synthesis and Electrochemical Behaviour of Aroylmethylidenetriphenylphosphoranes
Thies Thiemann,* Yumiko Tabuchi, Kazuya Arima and Shuntaro Mataka
Comments and Discussion

Company profiles and Product News
[s0001] InnoCentive seeks to lure researchers into solving posted chemical problems
Ann Thayer
Comments and Discussion



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